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- W2891570217 abstract "Abstract An efficient protocol for the construction of 3‐carbonyl functionalized 4‐pyrones has been developed using a transition‐metal free thermal cascade reaction of diazodicarbonyls with β‐enamino esters or β‐enamino ketones. This reaction proceeds via cascade carbene generation, ketene formation via thermal Wolff‐rearrangement, nucleophilic addition, intramolecular cyclization, and elimination. This protocol provides a rapid synthetic route to diverse 2,3,5‐trisubstituted 4‐pyrone derivatives. magnified image" @default.
- W2891570217 created "2018-09-27" @default.
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- W2891570217 date "2018-10-11" @default.
- W2891570217 modified "2023-10-14" @default.
- W2891570217 title "Transition-Metal-Free Regioselective Construction of Diverse 3-Carbonyl Functionalized 4-Pyrones<i>via</i>Thermal Wolff-Rearrangement of Diazodicarbonyls" @default.
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- W2891570217 doi "https://doi.org/10.1002/adsc.201800874" @default.
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