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- W2891572178 abstract "Elemental sulfur is a byproduct of petroleum refinement. Its abundance offers aninexpensive source of reagent. Inverse vulcanization combines sulfur with little monomer. Sulfurring opening above 159 °C, forms free radicals to bind monomers. Combining sulfur anddivinylbenzene (DVB) forms poly(S-DVB) after 30 minutes at 185 °C. Most monomers lack boilingpoints above 185 °C, so few monomers can be added. At lower temperatures, linear sulfur chainsin poly(S-DVB) cleave forming radicals which polymerize additional monomers. Diallyl, allyl,divinyl, and vinyl monomers with similar structures were incorporated into poly(S-DVB), solventfree at 90 °C. Polymerization was confirmed by 1H-NMR. Polymers were characterized by GPC todetermine molecular weight and DSC to find the glass transition temperature. Metal bindingstudies were conducted using these polysulfides. Poly(S-DVB) initiated polymer formation undermild reaction temperatures, solvent-free. Altering functionality and sulfur content enabledtailoring of material properties and affected metal binding efficiency." @default.
- W2891572178 created "2018-09-27" @default.
- W2891572178 creator A5038862196 @default.
- W2891572178 date "2018-07-21" @default.
- W2891572178 modified "2023-09-23" @default.
- W2891572178 title "Synthetic modification of poly(S-DVB) under solvent-free conditions at mild temperatures to incorporate additional monomers" @default.
- W2891572178 hasPublicationYear "2018" @default.
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