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- W2891592212 abstract "Abstract Perovskite Li x La 0.557 TiO 3 electrolytes in all‐solid‐state lithium batteries are operated under a voltage gradient, which potentially induces the electrochemical and mechanical instability. To simulate the properties of Li x La 0.557 TiO 3 ( LLTO ) under application relevant conditions, samples are charged (or discharged) to 0.2 V, 3.2 V, 4.0 V, and 4.5 V, respectively. The Li ion conductivity is 9.55 × 10 −5 S/cm at 3.2 V and decreases obviously to 2.54 × 10 −5 S/cm as the voltage increases to 4.5 V, whereas the value of the LLTO ‐0.2 V is between that of LLTO ‐3.2 V and LLTO ‐4.0 V. In terms of mechanical behavior, elastic modulus ( E ), hardness ( H ), and fracture toughness ( K IC ) of LLTO operated at different voltages are also tested using depth‐sensitive indentation. The results can be used in the designing, monitoring and also improving of the battery cells." @default.
- W2891592212 created "2018-09-27" @default.
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- W2891592212 date "2018-09-19" @default.
- W2891592212 modified "2023-10-11" @default.
- W2891592212 title "Electrochemical and mechanical stability of Li<sub><i>x</i></sub>La<sub>0.557</sub>TiO<sub>3‐<i>δ</i></sub> perovskite electrolyte at various voltages" @default.
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- W2891592212 doi "https://doi.org/10.1111/jace.16049" @default.
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