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• W2891598252 abstract "Concise, enantioselective, and divergent syntheses of alstoscholarisines A and E are presented in 8 and 9 steps, respectively; alstoscholarisine E has never been accessed before. A boron-mediated aldol reaction and Rh-catalyzed cycloisomerization were exploited to access stereoisomers 8 and 9 as key intermediates. The challenging sterically congested alstoscholarisine core was furnished by a reductive transannular cyclization in the final steps. This strategy was also used for the syntheses of enantiomers of alstoscholarisines A and E." @default.
• W2891598252 created "2018-09-27" @default.
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• W2891598252 date "2018-09-20" @default.
• W2891598252 modified "2023-09-27" @default.
• W2891598252 title "Enantioselective and Divergent Syntheses of Alstoscholarisines A, E and Their Enantiomers" @default.
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• W2891598252 doi "https://doi.org/10.1021/acs.orglett.8b02679" @default.
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