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- W2891603982 abstract "Indium demand has increased with the development of new 21st century technologies. The association of indium deposits with felsic igneous rocks suggests a need for increased research on the behavior of indium in magmatic-hydrothermal systems. In order to better understand the relationship between igneous processes and the formation of indium-bearing deposits, experiments have been conducted at 750 and 800 °C and 100 MPa to constrain the partitioning of indium between ferromagnesian (biotite and amphibole) minerals and felsic melts. The partition coefficient DInBt/Melt ranges from 0.6 ± 0.1 (1 σm (standard deviation of the mean)) to 16 ± 3 (1 σm). The variation in DInBt/Melt is a function of XAnniteBt (the proportion of Fe2+ in the octahedral site), tetrahedral aluminum, and titanium, such that DInBt/Melt decreases with increasing XAnniteBt, tetrahedral aluminum, and titanium. DInAmp/Melt has a mean of 36 ± 4 (1 σm) and composition has only a minor effect on the magnitude of DInAmp/Melt. Additionally, an aqueous volatile phase was recovered from select experiments, which provides an initial constraint on DInVapor/Melt. DInVapor/Melt can be influenced by the chlorine content of both the vapor and melt, and is estimated to be ~17 ± 5 (1 σm). Theoretical considerations suggest that DInBt/Melt can be affected above and beyond the effect of XAnniteBt by water fugacity and the activity of the sanidine component in the system. Theoretical considerations suggest that DInAmp/Melt can be affected by the activities of diopside, anorthite, and enstatite in the system and the fugacity of water. These results suggest that the amount of magmatically-derived indium available for ore formation is a function of the proportion of ferromagnesian minerals in the crystallization products of the magma." @default.
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- W2891603982 date "2018-11-01" @default.
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- W2891603982 title "Partitioning of indium between ferromagnesian minerals and a silicate melt" @default.
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- W2891603982 doi "https://doi.org/10.1016/j.chemgeo.2018.08.020" @default.
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