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- W2891605687 abstract "The use of 4,4′-[oxalylbis(azanediyl)]bis(2-hydroxybenzoic acid) (H6L1) in the Ba2+ chemistry has afforded a 3D polymer, namely [Ba(H2L2)(H2O)]n (1), which is based on H2L22– anions derived by the in-situ metal-assisted transformation of H6L1. The neutral H4L2 [4-(carboxyformamido)-2-hydroxybenzoic acid] ligand was isolated from 1 and characterized by spectroscopic methods. Polymer 1 is based on edge and face-sharing BaO10 polyhedra which create an inorganic layer pillared to the third dimension by the organic ligands and has been classified as an I2O1 framework. The topological analysis of 1 provided an opportunity to introduce a method for the deconstruction of I2O1 frameworks by adopting principles applied in the deconstruction of Metal-Organic-Frameworks (MOFs) with rod Secondary Building Units (SBUs). A detailed discussion and insights for the proper use of the ImOn notation which finds application in describing the dimensionality in MOFs, is also provided." @default.
- W2891605687 created "2018-09-27" @default.
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- W2891605687 date "2018-10-16" @default.
- W2891605687 modified "2023-09-23" @default.
- W2891605687 title "An I <sup>2</sup> O <sup>1</sup> Barium Framework Derived from an In‐Situ Metal‐Assisted Ligand Transformation" @default.
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- W2891605687 doi "https://doi.org/10.1002/ejic.201800866" @default.
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