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- W2891611419 abstract "Abstract New supramolecular ligands containing an acyl guanidine function were designed based on the strategy of increasing the π‐acceptor ability of phosphine ligands by introducing electron‐withdrawing groups. By applying this novel catalytic system, a general protocol for the Rh‐catalysed hydroformylation‐hydrogenation of unsymmetrical internal alkynes, functionalized with a carboxylic acid, was found to furnish aliphatic aldehydes in high regio‐ and chemoselectivities. Control experiments confirm the enzyme‐like supramolecular catalyst mode of action." @default.
- W2891611419 created "2018-09-27" @default.
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- W2891611419 date "2018-10-12" @default.
- W2891611419 modified "2023-10-03" @default.
- W2891611419 title "Tandem Regioselective Hydroformylation-Hydrogenation of Internal Alkynes Using a Supramolecular Catalyst" @default.
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- W2891611419 doi "https://doi.org/10.1002/anie.201809073" @default.
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