FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2891679365> ?p ?o ?g. }

• W2891679365 abstract "Electronic energy transfer is widely used as a molecular ruler to interrogate the structure of biomacromolecules, and performs a key task in photosynthesis by transferring collected energy through specialized pigment–protein complexes. Förster theory, introduced over 70 years ago, allows linking transfer rates to simple structural and spectroscopic properties of the energy‐transferring molecules. In biosystems, however, significant deviations from Förster behavior often arise due to breakdown of the ideal dipole approximation, dielectric screening effects due to the biological environment, or departure from the weak‐coupling regime. In this review, we provide a concise overview of advances in simulations of energy transfer in biomacromolecules that allow overcoming the main limitations of Förster theory. We first discuss advances in quantum chemical methods to compute electronic couplings, their extension to multiscale formulations to include screening effects, and strategies to treat the interplay between coupling fluctuations and energy transfer dynamics. We then examine the spectral overlap term, and how this quantity can be estimated from simulations of the spectral density of exciton–phonon coupling. Finally, we discuss rate theories that can describe energy transfers in situations where strong coupling leads to delocalized excitions, a common situation found in closely packed multichromophoric systems such as photosynthetic complexes and nucleic acids. This article is categorized under: Structure and Mechanism > Computational Biochemistry and Biophysics Theoretical and Physical Chemistry > Spectroscopy" @default.
• W2891679365 created "2018-09-27" @default.
• W2891679365 creator A5041412476 @default.
• W2891679365 creator A5064134375 @default.
• W2891679365 creator A5076761253 @default.
• W2891679365 creator A5087185165 @default.
• W2891679365 date "2018-09-13" @default.
• W2891679365 modified "2023-10-14" @default.
• W2891679365 title "Electronic energy transfer in biomacromolecules" @default.
• W2891679365 cites W1127167206 @default.
• W2891679365 cites W1592546336 @default.
• W2891679365 cites W1964735992 @default.
• W2891679365 cites W1969377344 @default.
• W2891679365 cites W1973264894 @default.
• W2891679365 cites W1973699439 @default.
• W2891679365 cites W1975267028 @default.
• W2891679365 cites W1977964292 @default.
• W2891679365 cites W1979946091 @default.
• W2891679365 cites W1980809949 @default.
• W2891679365 cites W1981194820 @default.
• W2891679365 cites W1981740386 @default.
• W2891679365 cites W1982972906 @default.
• W2891679365 cites W1983149290 @default.
• W2891679365 cites W1983968967 @default.
• W2891679365 cites W1988284025 @default.
• W2891679365 cites W1989310356 @default.
• W2891679365 cites W1995337068 @default.
• W2891679365 cites W1997151511 @default.
• W2891679365 cites W1997735178 @default.
• W2891679365 cites W1998045383 @default.
• W2891679365 cites W1998520078 @default.
• W2891679365 cites W2002435812 @default.
• W2891679365 cites W2005942991 @default.
• W2891679365 cites W2006442889 @default.
• W2891679365 cites W2008929933 @default.
• W2891679365 cites W2010660548 @default.
• W2891679365 cites W2011895693 @default.
• W2891679365 cites W2012839646 @default.
• W2891679365 cites W2013558981 @default.
• W2891679365 cites W2013994990 @default.
• W2891679365 cites W2016402524 @default.
• W2891679365 cites W2022778461 @default.
• W2891679365 cites W2022793917 @default.
• W2891679365 cites W2022855606 @default.
• W2891679365 cites W2023769866 @default.
• W2891679365 cites W2024591590 @default.
• W2891679365 cites W2030745215 @default.
• W2891679365 cites W2032455643 @default.
• W2891679365 cites W2032651181 @default.
• W2891679365 cites W2035579953 @default.
• W2891679365 cites W2035838814 @default.
• W2891679365 cites W2040883303 @default.
• W2891679365 cites W2042003250 @default.
• W2891679365 cites W2045345626 @default.
• W2891679365 cites W2048268006 @default.
• W2891679365 cites W2048710211 @default.
• W2891679365 cites W2050929241 @default.
• W2891679365 cites W2053839673 @default.
• W2891679365 cites W2059722687 @default.
• W2891679365 cites W2061674188 @default.
• W2891679365 cites W2062326570 @default.
• W2891679365 cites W2067160667 @default.
• W2891679365 cites W2067177268 @default.
• W2891679365 cites W2069483082 @default.
• W2891679365 cites W2072313843 @default.
• W2891679365 cites W2074443308 @default.
• W2891679365 cites W2077030037 @default.
• W2891679365 cites W2078617785 @default.
• W2891679365 cites W2079202877 @default.
• W2891679365 cites W2079954914 @default.
• W2891679365 cites W2081133668 @default.
• W2891679365 cites W2081446514 @default.
• W2891679365 cites W2081620547 @default.
• W2891679365 cites W2082321237 @default.
• W2891679365 cites W2082479893 @default.
• W2891679365 cites W2090061616 @default.
• W2891679365 cites W2090664836 @default.
• W2891679365 cites W2090793006 @default.
• W2891679365 cites W2091284076 @default.
• W2891679365 cites W2094517427 @default.
• W2891679365 cites W2097552134 @default.
• W2891679365 cites W2097668319 @default.
• W2891679365 cites W2099208506 @default.
• W2891679365 cites W2100798359 @default.
• W2891679365 cites W2104017292 @default.
• W2891679365 cites W2107637161 @default.
• W2891679365 cites W2109246296 @default.
• W2891679365 cites W2114983937 @default.
• W2891679365 cites W2118881986 @default.
• W2891679365 cites W2124861434 @default.
• W2891679365 cites W2129525628 @default.
• W2891679365 cites W2132677630 @default.
• W2891679365 cites W2133294519 @default.
• W2891679365 cites W2133634382 @default.
• W2891679365 cites W2140886269 @default.
• W2891679365 cites W2142080511 @default.
• W2891679365 cites W2148519562 @default.
• W2891679365 cites W2158426902 @default.
• W2891679365 cites W2174855856 @default.
• W2891679365 cites W2228495421 @default.

• next