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- W2891761875 abstract "Although boron-containing radicals are promising materials for molecular electronic devices, the electronic effect of the σ-donating yet π-accepting boron center on the stability of open-shell species has been less discussed. In this work, the role of a tricoordinate boron center in π-conjugated radicals was explored through electron paramagnetic resonance measurement of several boron-linked bisphenol radicals and diradicals. Replacing the bridging methine fragment of a neutral Galvinoxyl radical with an arylboryl group led to the corresponding boron-linked radical anion that requires excessive steric protection at the boron center to be persistent in solution. Experimental and theoretical investigations revealed that the introduction of boron would diminish the quinoidal character of the phenoxyl radical and increase both the electrophilicity and nucleophilicity of the open-shell species. Therefore, it is important to consider the steric protection of the boron center in boron-containing π-conjugated organic radicals." @default.
- W2891761875 created "2018-09-27" @default.
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- W2891761875 date "2018-09-04" @default.
- W2891761875 modified "2023-10-18" @default.
- W2891761875 title "Destabilizing Character of a π-Conjugated Boron Center in Bisphenol Radicals" @default.
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- W2891761875 doi "https://doi.org/10.1021/acs.inorgchem.8b01865" @default.
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