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• W2891773249 abstract "Generation processes of the third phase and the carbanion for Horner–Wadsworth–Emmons (HWE) reaction of the “weakly acidic” substrate in the third-liquid phase-transfer catalysis (TLPTC) system were investigated. The third phase consisted of Et2PO4– (diethyl phosphate anion), Br– and TBA+ (tetrabutylammonium), and molar content of Et2PO4– was 6.65 times greater than that of TBA+. The true catalyst was the complex of TBA+Et2PO4– and TBAB. Excess Et2PO4– could be associated with TBA+Et2PO4–, resulting in generation of the third phase. The “true” catalyst showed a higher catalytic activity and the reaction equilibrium constant for the third-phase cycle was 26 times greater than that for the organic-phase cycle. Results from background reaction, interfacial tension, and hydrogen–deuterium exchange reaction experiments suggested that the phosphonate were deprotonated by “naked” OH–, without help of the catalyst. These novel generation processes of the third phase and the carbanion were key factors for this efficient TLPTC system." @default.
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• W2891773249 date "2018-09-17" @default.
• W2891773249 modified "2023-10-14" @default.
• W2891773249 title "Catalytic Process for the Hydroxide-Initiated Reaction of the “Weakly Acidic” Substrate in the Third-Liquid Phase-Transfer Catalytic System" @default.
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• W2891773249 doi "https://doi.org/10.1021/acs.iecr.8b02119" @default.
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