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- W2891780231 endingPage "97" @default.
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- W2891780231 abstract "The synthesis and characterization of three metalla-rectangles of the general formula [Ru4(η6-p-cymene)4(μ4-clip)2(μ2-Lanthr)2][CF3SO3]4 (Lanthr: 9,10-bis(3,3’-ethynylpyridyl) anthracene; clip = oxa: oxalato; dobq: 2,5-dioxido-1,4-benzoquinonato; donq: 5,8-dioxido-1,4-naphthoquinonato) are presented. The molecular structure of the metalla-rectangle [Ru4(η6-p-cymene)4(μ4-oxa)2(μ2-Lanthr)2]4+ has been confirmed by the single-crystal X-ray structure analysis of [Ru4(η6-p-cymene)4(μ4-oxa)2(μ2-Lanthr)2][CF3SO3]4 · 4 acetone (A2 · 4 acetone), thus showing the anthracene moieties to be available for reaction with oxygen. While the formation of the endoperoxide form of Lanthr was observed in solution upon white light irradiation, the same reaction does not occur when Lanthr is part of the metalla-assemblies." @default.
- W2891780231 created "2018-09-27" @default.
- W2891780231 creator A5018036952 @default.
- W2891780231 creator A5049504296 @default.
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- W2891780231 creator A5082586824 @default.
- W2891780231 date "2018-09-12" @default.
- W2891780231 modified "2023-09-28" @default.
- W2891780231 title "Arene Ruthenium Metalla-Assemblies with Anthracene Moieties for PDT Applications" @default.
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- W2891780231 doi "https://doi.org/10.3390/inorganics6030097" @default.
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