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- W2891805666 abstract "Metal sulfides are promising anode materials for lithium ion batteries (LIBs) and sodium ion batteries (SIBs) owing to their high theoretical capacity and good reaction reversibility upon lithiation/delithiation and sodiation/desodiation. However, the practical application of metal sulfides is severely hindered by its poor conductivity and huge volume change during cycling. Herein, a three dimensional hierarchical architecture is rational designed and synthesized through incorporating ZnS-SnS heterostructure encapsulated by carbon shell into graphene matrix. The interconnected conductive networks from the graphene skeleton and outer coating carbon can not only provide a high efficient transfer path for electron and ion, but also accommodate the volume variation effectively upon charging/discharging. Additionally, the in-situ constructed ZnS-SnS heterostructures provide extra charge transfer driving force because of a built-in electric field. Consequently, the as obtained [email protected] hollow nanoboxes wrapped by grpahene show high specific capacity, long cycle lifetime and excellent rate performance when applied for anodes of LIBs and SIBs." @default.
- W2891805666 created "2018-09-27" @default.
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- W2891805666 date "2019-01-01" @default.
- W2891805666 modified "2023-10-12" @default.
- W2891805666 title "Heterostructured SnS-ZnS@C hollow nanoboxes embedded in graphene for high performance lithium and sodium ion batteries" @default.
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- W2891805666 doi "https://doi.org/10.1016/j.cej.2018.09.131" @default.
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