FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2891816471> ?p ?o ?g. }

• W2891816471 endingPage "89" @default.
• W2891816471 startingPage "80" @default.
• W2891816471 abstract "Abstract 5-Hydroxymethyl-2-furfural (HMF) is a key platform molecule for biomass utilization. The HMF derivative 2,5-furandicarboxylic acid (FDCA) by oxidation of HMF is a promising alternative for terephthalic acid as a monomer in polyethylene terephthalate. However, due to the facile purification of dimethyl furan-2,5-dicarboxylate (DMFD), an oxidative esterification derivative of HMF, is more desirable. In this work, supported Au–Cu bimetallic catalysts with Au–CuOx (x = 0–1) nanohybrids were prepared by a reduction–oxidation pretreatment strategy. The as-prepared catalysts were used for the oxidative esterification of HMF into DMFD under base-free conditions using oxygen as sole oxidant. Activity tests showed that the optimized Au–Cu/γ-Al2O3 catalyst displayed a remarkably high DMFD yield of up to 98% and a turnover frequency (TOF) value of 243 h–1, whereas the monometallic Au and Cu catalysts exhibited poor performance. Various characterizations confirmed the strong interaction between Au nanoparticles and CuOx species, and their synergistic effect on the enhanced performance of HMF oxidative esterification. The reduction–oxidation pretreatment promoted the dispersion of CuOx and intensified the interaction of Au nanoparticles with CuOx. A plausible reaction mechanism for the oxidative esterification of HMF over Au–Cu/γ-Al2O3 was proposed. This work provided new insights into the effect of reduction–oxidation pretreatment on the fabrication of supported Au–CuOx nanohybrids for the production of DMFD by HMF oxidative esterification." @default.
• W2891816471 created "2018-09-27" @default.
• W2891816471 creator A5020338572 @default.
• W2891816471 creator A5036002985 @default.
• W2891816471 creator A5043519947 @default.
• W2891816471 creator A5052461254 @default.
• W2891816471 creator A5085295097 @default.
• W2891816471 creator A5088709415 @default.
• W2891816471 date "2018-10-01" @default.
• W2891816471 modified "2023-10-16" @default.
• W2891816471 title "Fabrication of supported Au-CuO nanohybrids by reduction-oxidation strategy for efficient oxidative esterification of 5-hydroxymethyl-2-furfural into dimethyl furan-2,5-dicarboxylate" @default.
• W2891816471 cites W1435560705 @default.
• W2891816471 cites W1884244646 @default.
• W2891816471 cites W1944207547 @default.
• W2891816471 cites W1981123696 @default.
• W2891816471 cites W1989102107 @default.
• W2891816471 cites W1992672011 @default.
• W2891816471 cites W2002529545 @default.
• W2891816471 cites W2003518440 @default.
• W2891816471 cites W2004393887 @default.
• W2891816471 cites W2007743549 @default.
• W2891816471 cites W2013319574 @default.
• W2891816471 cites W2044479511 @default.
• W2891816471 cites W2047436432 @default.
• W2891816471 cites W2048162611 @default.
• W2891816471 cites W2048229893 @default.
• W2891816471 cites W2050478475 @default.
• W2891816471 cites W2055712688 @default.
• W2891816471 cites W2056272463 @default.
• W2891816471 cites W2073462983 @default.
• W2891816471 cites W2077848988 @default.
• W2891816471 cites W2079584659 @default.
• W2891816471 cites W2085257348 @default.
• W2891816471 cites W2086266880 @default.
• W2891816471 cites W2112163651 @default.
• W2891816471 cites W2119970259 @default.
• W2891816471 cites W2123276298 @default.
• W2891816471 cites W2123457457 @default.
• W2891816471 cites W2126452174 @default.
• W2891816471 cites W2127241066 @default.
• W2891816471 cites W2138284188 @default.
• W2891816471 cites W2143549766 @default.
• W2891816471 cites W2260547901 @default.
• W2891816471 cites W2279139347 @default.
• W2891816471 cites W2292587459 @default.
• W2891816471 cites W2329501275 @default.
• W2891816471 cites W2345180661 @default.
• W2891816471 cites W2468845659 @default.
• W2891816471 cites W2490314549 @default.
• W2891816471 cites W2495475553 @default.
• W2891816471 cites W2507167093 @default.
• W2891816471 cites W2522943755 @default.
• W2891816471 cites W2528655061 @default.
• W2891816471 cites W2550192683 @default.
• W2891816471 cites W2561366603 @default.
• W2891816471 cites W2579009013 @default.
• W2891816471 cites W2586524801 @default.
• W2891816471 cites W2589054971 @default.
• W2891816471 cites W2597316431 @default.
• W2891816471 cites W2604090153 @default.
• W2891816471 cites W2607158828 @default.
• W2891816471 cites W2607457567 @default.
• W2891816471 cites W2612294640 @default.
• W2891816471 cites W2613698088 @default.
• W2891816471 cites W2622804449 @default.
• W2891816471 cites W2729748983 @default.
• W2891816471 cites W2735581600 @default.
• W2891816471 cites W2751700046 @default.
• W2891816471 cites W2755715715 @default.
• W2891816471 cites W2781587340 @default.
• W2891816471 cites W2783290494 @default.
• W2891816471 doi "https://doi.org/10.1016/j.apcata.2018.09.004" @default.
• W2891816471 hasPublicationYear "2018" @default.
• W2891816471 type Work @default.
• W2891816471 sameAs 2891816471 @default.
• W2891816471 citedByCount "25" @default.
• W2891816471 countsByYear W28918164712019 @default.
• W2891816471 countsByYear W28918164712020 @default.
• W2891816471 countsByYear W28918164712021 @default.
• W2891816471 countsByYear W28918164712022 @default.
• W2891816471 countsByYear W28918164712023 @default.
• W2891816471 crossrefType "journal-article" @default.
• W2891816471 hasAuthorship W2891816471A5020338572 @default.
• W2891816471 hasAuthorship W2891816471A5036002985 @default.
• W2891816471 hasAuthorship W2891816471A5043519947 @default.
• W2891816471 hasAuthorship W2891816471A5052461254 @default.
• W2891816471 hasAuthorship W2891816471A5085295097 @default.
• W2891816471 hasAuthorship W2891816471A5088709415 @default.
• W2891816471 hasConcept C111335779 @default.
• W2891816471 hasConcept C136525101 @default.
• W2891816471 hasConcept C142724271 @default.
• W2891816471 hasConcept C161790260 @default.
• W2891816471 hasConcept C178790620 @default.
• W2891816471 hasConcept C185592680 @default.
• W2891816471 hasConcept C204787440 @default.
• W2891816471 hasConcept C206139338 @default.
• W2891816471 hasConcept C2524010 @default.
• W2891816471 hasConcept C2778659115 @default.

• next