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• W2891817830 abstract "Recently, layered perovskites attracted great attention for its excellent stability and light-emitting property. However, most of them rely on the toxic element lead and their emission quantum yields are generally low. Here, a unique hollow two-dimensional perovskite was developed in which the organic hexamethylene diamines (C6H18N22+) strongly coupled with distorted tin bromide anions (SnBr64-). This toxic-free low-dimensional tin perovskite exhibits a broadband emission in the visible region with a high luminescence quantum yield of 86%. First-principles calculation indicate the broadband emission is associated with the recombination of self-trapped excitons. And the emission is related to the geometry of tin bromide anions. An ultraviolet light-pumped white light emitting diode with excellent color-rendering index of 94 was fabricated using it together with a commercially available blue phosphor." @default.
• W2891817830 created "2018-09-27" @default.
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• W2891817830 date "2018-09-07" @default.
• W2891817830 modified "2023-10-16" @default.
• W2891817830 title "Organic−Inorganic Layered and Hollow Tin Bromide Perovskite with Tunable Broadband Emission" @default.
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• W2891817830 doi "https://doi.org/10.1021/acsami.8b07673" @default.
• W2891817830 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30192511" @default.
• W2891817830 hasPublicationYear "2018" @default.
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