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- W2891826321 abstract "Host-guest interactions are widely employed in constructing responsive materials, although less is known to manipulate the chiral property of materials using such host-guest dynamics. With the supramolecular self-assembly based on β-cyclodextrin (β-CD) and alkyl amines (CH3(CH2)n-1NH2), we report that faster host-guest dynamics induces a dipole located above the cavity of β-CD, whereas slower dynamics create in-cavity dipole. These two scenarios correspond to negative and positive chiral signals, respectively. Considering that a larger fraction of amines facilitates faster exchange between the threaded and unthreaded amines, the chiral signal for the right-handed helical ribbons can be manipulated simply by alternatively increasing the fraction of amines and β-CD. Excitingly, enzyme responsive supramolecular chirality is obtained as a result of shifting the molar ratio by enzyme triggered hydrolysis of β-CD. We expect that this strategy may open up an area of rationally designed chiral supramolecular materials based on host-guest chemistry." @default.
- W2891826321 created "2018-09-27" @default.
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- W2891826321 date "2018-09-06" @default.
- W2891826321 modified "2023-10-17" @default.
- W2891826321 title "Reversible Manipulation of Supramolecular Chirality using Host-Guest Dynamics between β-Cyclodextrin and Alkyl Amines" @default.
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- W2891826321 doi "https://doi.org/10.1002/chem.201803638" @default.
- W2891826321 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30256477" @default.
- W2891826321 hasPublicationYear "2018" @default.
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