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• W2891833566 endingPage "11929" @default.
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• W2891833566 abstract "The effect of the synthesis conditions on the structure and guest-responsive properties of a gate pressure metal-organic framework (MOF) with composition [Cu(4,4'-bipy)2(BF4)2] n (4,4'-bipy = 4,4'-bipyridine), also known as ELM-11 (ELM = elastic layer material) was investigated. Two different batches of ELM-11, synthesized from water-methanol and water-acetonitrile solutions, have been entirely characterized by PXRD, nitrogen (77 K) and carbon dioxide (195 K) physisorption, elemental analysis, DRIFT, TG, and SEM. Both ELM-11 samples were studied by electron paramagnetic resonance (EPR) spectroscopy in order to follow the change in the local structure of the copper ion during the activation and resolvation. Continuous wave X-band EPR measurements on powder samples provided an elongated octahedral coordination symmetry of the cupric ions and revealed different axial ligands in the as-synthesized and activated forms in both bulk samples of ELM-11. One of the procedures was amended in order to slow down the crystallization that allows isolation of single crystals of two polymorphic modifications of Cu-4,4'-bipyridine coordination polymers, namely [Cu(4,4'-bipy)2(CH3CN)2](BF4)2 and [Cu2O(4,4'-bipy)3(CH3CN)4](BF4)2, one of which shows a crystal structure similar to that of ELM-11. Further single-crystal EPR experiments on the as-synthesized material [Cu(4,4'-bipy)2(CH3CN)2](BF4)2 revealed the orientation of the g tensor of the cupric ions and proved that layers of acetonitrile-synthesized ELM-11 are arranged perpendicularly to the crystallographic c axis." @default.
• W2891833566 created "2018-09-27" @default.
• W2891833566 creator A5030419910 @default.
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• W2891833566 date "2018-09-12" @default.
• W2891833566 modified "2023-10-18" @default.
• W2891833566 title "Elucidating the Formation and Transformation Mechanisms of the Switchable Metal–Organic Framework <b>ELM-11</b> by Powder and Single-Crystal EPR Study" @default.
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• W2891833566 doi "https://doi.org/10.1021/acs.inorgchem.8b01241" @default.
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• W2891833566 hasPublicationYear "2018" @default.
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