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• W2891855313 abstract "The first catalytic asymmetric formation of a fulvene from a racemic α,α-disubstituted aldehyde has been developed. Dynamic kinetic resolution of rac-2-phenylpropanal by a simple, modularly designed supramolecular organocatalyst consisting of inexpensive components has been established, producing the desired fulvene in good yields and moderate enantioselectivities. Herein we propose a mechanistic interpretation of the observed solvent- and additive-induced stereoselectivity reversal." @default.
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• W2891855313 date "2018-10-01" @default.
• W2891855313 modified "2023-09-27" @default.
• W2891855313 title "Organocatalytic asymmetric fulvene formation" @default.
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• W2891855313 doi "https://doi.org/10.1016/j.tet.2018.09.016" @default.
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