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- W2891890825 abstract "在288.15-318.15 K温度范围内测定了不同浓度离子液体1-乙基-3-甲基咪唑醋酸盐（[C2mim][OAc]）水溶液的表面张力和密度;在改进李以圭等人的溶液表面张力模型基础上,提出摩尔表面Gibbs自由能新概念,建立了摩尔表面Gibbs自由能随溶液浓度变化的线性经验方程,利用这个经验方程估算了[C2mim][OAc]水溶液的摩尔表面Gibbs自由能,并进一步预测了该溶液的表面张力,其预测值与相应的表面张力实验值高度相关并非常相似。由此可见,摩尔表面Gibbs自由能与等张比容极其类似,可能成为预测离子液体及其溶液性质的一种新的半经验方法。在指定溶液浓度下,根据溶液的摩尔表面Gibbs自由能随温度呈线性变化的规律,得到了新的Eotvos方程,与传统的Eotvos方程相比,新Eotvos方程的每一个参数都有明确的物理意义：斜率的负值是摩尔表面熵,截距是摩尔表面焓,在指定浓度的溶液中摩尔表面焓几乎不随温度变化。" @default.
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- W2891890825 date "2016-01-01" @default.
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- W2891890825 title "Molar Surface Gibbs Free Energy of the Aqueous Solution of the Ionic Liquid [C<sub>2</sub>mim][OAc]" @default.
- W2891890825 doi "https://doi.org/10.3866/pku.whxb201602232" @default.
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