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- W2891898728 endingPage "6026" @default.
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- W2891898728 abstract "For the first time, a desymmetrization strategy empowered the assembly of a class of optically pure spirooxindole–urazoles possessing an N-Ar stereogenic axis via remote control of axial chirality in an asymmetric three-component reaction. This transformation was realized by a tandem bisthiourea-catalyzed asymmetric Diels–Alder reaction and substrate-controlled asymmetric ene reaction. The driving force derived from aromatization and the high reactivity of 4-aryl-1,2,4-triazole-3,5-dione enophiles mediated the occurrence of the successive ene reaction under mild conditions." @default.
- W2891898728 created "2018-09-27" @default.
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- W2891898728 date "2018-09-17" @default.
- W2891898728 modified "2023-10-16" @default.
- W2891898728 title "Remote Control of Axial Chirality: Synthesis of Spirooxindole–Urazoles via Desymmetrization of ATAD" @default.
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- W2891898728 doi "https://doi.org/10.1021/acs.orglett.8b02361" @default.
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