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• W2891910212 abstract "Abstract The synthesis of pyrroles under mild conditions using sulfonic acid‐functionalized β ‐Cyclodextrin ( β ‐CD) as a supramolecular catalyst under aqueous conditions is demonstrated. Good to excellent conversion of various amines into pyrroles was observed without any side product formation. CD was found to play a dual role as a phase transfer reagent through inclusion as well as an acid catalyst thereby facilitating the smooth conversions of reactants. The advantages of this protocol are mild reaction conditions, sustainable catalyst and use of non‐toxic solvent water. Notably, the catalyst can be easily recovered and reused up to five cycles without any loss of catalytic activity. The developed protocol was successfully used as a key step for the formal synthesis of the alkaloid natural product Polygonatine." @default.
• W2891910212 created "2018-09-27" @default.
• W2891910212 creator A5002514242 @default.
• W2891910212 creator A5078443572 @default.
• W2891910212 date "2018-09-11" @default.
• W2891910212 modified "2023-09-26" @default.
• W2891910212 title "Biomimetic Clauson-Kass and Paal-Knorr Pyrrole Synthesis Using <i>β</i> -Cyclodextrin-SO₃ H under Aqueous and Neat Conditions - Application to Formal Synthesis of Polygonatine^†" @default.
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• W2891910212 doi "https://doi.org/10.1002/slct.201801559" @default.
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