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• W2891923369 endingPage "12194" @default.
• W2891923369 startingPage "12187" @default.
• W2891923369 abstract "The compounds [Ru(acac)2(L)] (1) and [Ru2(acac)4(μ-L)] (2) with acac– = acetylacetonato and L = thioindigo were characterized crystallographically with a cis-configurated L and O,O′-coordinated metal in 1 and with trans-configurated L and two S,O-coordinated bridged ruthenium centers for 2. The electronic structures of 1 and 2 were confirmed by spectroscopy and density functional theory calculations, suggesting considerable metal-to-ligand electron transfer resulting in the formation of the thioindigo radical anion and oxidized metal(s). UV–Vis–Near-IR and IR (spectro)electrochemistry was used to investigate charged forms 1n (n = 1+, 1−) and 2n (n = 1+, 1–, 2−), which reveal electron transfer activity of both the metal and the thioindigo ligand as well as sizable orbital mixing. An intense near-IR absorption is observed for 2– at 2180 nm. The remarkable ligand properties of thioindigo are being discussed in connection to related coordination compounds of indigo derivatives such as dehydroindigo and corresponding (“Nindigo”) diimines." @default.
• W2891923369 created "2018-09-27" @default.
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• W2891923369 date "2018-09-10" @default.
• W2891923369 modified "2023-10-17" @default.
• W2891923369 title "Mononuclear and Dinuclear Ruthenium Complexes of <i>cis</i>- and <i>trans</i>-Thioindigo: Geometrical and Electronic Structure Analyses" @default.
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• W2891923369 doi "https://doi.org/10.1021/acs.inorgchem.8b01829" @default.
• W2891923369 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30198711" @default.
• W2891923369 hasPublicationYear "2018" @default.
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