Matches in SemOpenAlex for { <https://semopenalex.org/work/W2891936235> ?p ?o ?g. }
- W2891936235 abstract "The reaction of the tetranuclear iron complex [ $$upmu _{4}$$ -Sulfido-bis{( $$upmu $$ -2-furylmethanethiolato)bis[tricarbonyliron](Fe—Fe)}] 1 with $$hbox {PPh}_{3}$$ was explored. The reaction leads to the formation of the mono-substituted complex [ $$hbox {Fe}_{2}(upmu $$ -2-furylmethanethiolate) $$_{2}(hbox {CO})_{5}(hbox {PPh}_{3})$$ ] 2. X-ray crystal structure has been reported for complex 2. Complexes 1 and 2 were found to be active catalysts for proton reduction. Complexes 1 and 2 showed comparable catalytic activity for proton reduction to dihydrogen. SYNOPSIS Monothiolate-bridged, all carbonyl tetranuclear iron complex [ $$upmu _{4}$$ -Sulfido-bis{( $$upmu $$ -2-furylmethanethiolato)bis[tricarbonyliron](Fe—Fe)}] 1 and phosphine-substituted diiron complex [ $$hbox {Fe}_{2}(upmu $$ -furylmethanethiolate) $$_{2}(hbox {CO})_{5}(hbox {PPh}_{3})$$ ] 2 have been investigated for electrocatalytic proton reduction." @default.
- W2891936235 created "2018-09-27" @default.
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- W2891936235 date "2018-09-01" @default.
- W2891936235 modified "2023-09-24" @default.
- W2891936235 title "A tetranuclear iron complex: substitution with triphenylphosphine ligand and investigation into electrocatalytic proton reduction" @default.
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- W2891936235 doi "https://doi.org/10.1007/s12039-018-1529-x" @default.
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