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- W2891955976 abstract "Abstract A kinetic investigation was carried out on the utilization of H2S for the synthesis of bis-(2-phenylethyl) sulfide (PES) using ionic liquid catalyst trihexyltetradecylphosphonium chloride as a phase transfer catalyst. The method involved the absorption of H2S into aqueous N-methyldiethanolamine (MDEA) which is followed by reaction of this aqueous H2S-laden MDEA with organic reactant 2-bromoethylbenzene (2-BEB) to yield PES under liquid–liquid (L–L) phase transfer catalytic condition. The effect of various reaction parameters on the conversion of 2-BEB was studied and the product selectivity was found as 100%. A suitable reaction mechanism involving the possible paths of product formation was proposed. A novel mathematical model was developed to explain the experimental findings. This method will be helpful in overcoming the cost of disposal of organic solvents which have been used often in multiphase organic synthesis." @default.
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- W2891955976 date "2018-12-01" @default.
- W2891955976 modified "2023-09-24" @default.
- W2891955976 title "Kinetic modeling on ionic liquid mediated bi-liquid phase transfer catalyzed synthesis of bis-(2-phenylethyl) sulfide with H2S-rich methyldiethanolamine" @default.
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- W2891955976 doi "https://doi.org/10.1016/j.molliq.2018.09.038" @default.
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