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- W2891972610 endingPage "11872" @default.
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- W2891972610 abstract "A nickel-catalyzed cyanation reaction of benzylic and allylic pivalate esters is reported using an air-stable Ni(II) precatalyst and substoichiometric quantities of Zn(CN)2. Alkene additives were found to inhibit catalysis, suggesting that avoiding β-hydride elimination side reactions is essential for productive catalysis. An enantioenriched allylic ester undergoes enantiospecific cross-coupling to produce an enantioenriched allylic nitrile. This method was applied to an efficient synthesis of (±)-naproxen from commercially available starting materials." @default.
- W2891972610 created "2018-09-27" @default.
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- W2891972610 date "2018-09-04" @default.
- W2891972610 modified "2023-10-03" @default.
- W2891972610 title "Nickel-Catalyzed Cyanation of Benzylic and Allylic Pivalate Esters" @default.
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- W2891972610 doi "https://doi.org/10.1021/acs.joc.8b01763" @default.
- W2891972610 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30179005" @default.
- W2891972610 hasPublicationYear "2018" @default.
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