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- W2891985445 abstract "Porous Li3V2(PO4)3@C/AB hollow microspheres have been synthesized in a large-scale using a combined method of spray drying and solid-state reaction. The structure and electrochemical properties of the Li3V2(PO4)3@C/AB samples are characterized by various physical characterization techniques as well as electrochemical measurements. XRD results reveal pure highly crystalline Li3V2(PO4)3 with the monoclinic structure. SEM and TEM images show the porous hollow structure and a uniform carbon coating layer of the samples. The sample with a carbon content of 8.94 wt% exhibits remarkable rate capability and long-term cycling performance, delivering an initial discharge capacity of 109.8 mAh g−1 at 1 C within a voltage range of 3–4.3 V versus Li/Li+, and a capacity retention of 98.5% over 200 cycles. Even at 20 C, the sample presents an initial discharge capacity of 95.8 mAh g−1 and a capacity retention of 71.8% after 2000 cycles. The remarkable cycling performance can be attributed to the synergistic effect of porous hollow structure and uniform carbon coating of Li3V2(PO4)3@C/AB cathode materials. This work demonstrates the porous Li3V2(PO4)3@C/AB hollow microspheres are promising cathode materials for practical application in lithium-ion batteries." @default.
- W2891985445 created "2018-09-27" @default.
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- W2891985445 date "2019-02-01" @default.
- W2891985445 modified "2023-10-15" @default.
- W2891985445 title "Large-scale synthesis of porous Li3V2(PO4)3@C/AB hollow microspheres with interconnected channel as high performance cathodes for lithium-ion batteries" @default.
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- W2891985445 doi "https://doi.org/10.1016/j.jallcom.2018.09.214" @default.
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