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• W2892014207 abstract "In joint dilute aqueous solutions of pullulan (PUL) and poly(sodium 4-styrenesulfonate) (PSS-Na) the Na+ ions of the polyelectrolyte interact so favorably with the monomeric units of PUL that isolated coils containing both types of macromolecules are formed upon dilution. When water is replaced against a 1 M solution of NaCl, this effect dies out because of the large surplus of Na+ ions. On the other hand, if the water contains increasing amounts of the respective counterpolymer instead of NaCl, the formation of mixed isolated coils is fostered, where a further diminution of the intrinsic viscosities is caused by the lower the solvent quality. The molar mass of PSS-Na plays an important role for the viscosities of the solutions in pure water. The reason lies in the different extent of the electrostatic self-shielding as a function of the polyelectrolyte concentration." @default.
• W2892014207 created "2018-09-27" @default.
• W2892014207 creator A5008700481 @default.
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• W2892014207 date "2018-09-17" @default.
• W2892014207 modified "2023-10-02" @default.
• W2892014207 title "Intrinsic Viscosities of Polymer Blends: Sensitive Probes of Specific Interactions between the Counterions of Polyelectrolytes and Uncharged Macromolecules" @default.
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• W2892014207 doi "https://doi.org/10.1021/acs.macromol.8b01422" @default.
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