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• W2892022449 abstract "The luminescent properties of europium(III) trifluoroacetate [Eu(TFA)3bipy·3Н2О]∙bipy (I), where TFA - trifluoroacetate anion and bipy - 2,2'bipyridyl were investigated. Despite the presence of two efficient antenna ligands in complex (bipy1 in europium coordination sphere and bipy2 in the outer-sphere) the complex displays weak luminescence. By employing density functional theory-based methods, the luminescence, electron structure, interligand interactions and the processes of energy transfer in I were investigated. The nature of the chemical bond in I was studied by the natural bond orbital analysis. The mechanism of luminescence weakening in the complex was ascertained: competitive energy transfer from coordinated bipy1 ligand on to outer-sphere bipy2 molecule results in appreciable weakening of the antenna effect." @default.
• W2892022449 created "2018-09-27" @default.
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• W2892022449 date "2019-01-01" @default.
• W2892022449 modified "2023-09-26" @default.
• W2892022449 title "Europium(III) complex with powerful antenna ligands: Interligand interaction" @default.
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• W2892022449 doi "https://doi.org/10.1016/j.saa.2018.09.012" @default.
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