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- W2892022904 abstract "Abstract An efficient strategy for the specific recognition of ellipsoidal fullerenes uses molecular containers with well‐designed three‐dimensional (3D) nanospaces. We describe the synthesis of a supramolecular double‐decker cage composed of shape‐persistent metallomacrocycles and pillar ligands. A discrete 3D nanospace was built within the molecular framework of the shape‐persistent‐macrocycle/bidentate‐pillar molecule. The single‐crystal structure of the supramolecular cage reveals a uniquely shaped inner cavity with a size and net volume (>670 Å 3 ) that are well matched to the shape and size of C 70 . The cage exhibited higher selectivity for C 70 over C 60 , the smaller carbon allotrope. We suggest that such C 70 ‐selective recognition is derived from multiple CH–π interactions between hydrogen atoms inside the cage and C 70 ." @default.
- W2892022904 created "2018-09-27" @default.
- W2892022904 creator A5020134496 @default.
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- W2892022904 date "2018-10-09" @default.
- W2892022904 modified "2023-10-14" @default.
- W2892022904 title "Specific and Oriented Encapsulation of Fullerene C<sub>70</sub> into a Supramolecular Double-Decker Cage Composed of Shape-Persistent Macrocycles" @default.
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- W2892022904 doi "https://doi.org/10.1002/anie.201809167" @default.
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