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- W2892028199 endingPage "4308" @default.
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- W2892028199 abstract "We report the synthesis of the first series of terminal phosphido iron complexes supported by a β‐diketiminato ligand (Dippnacnac) and their catalytic activity in dehydrocoupling of secondary phosphines. Anionic and neutral mono‐ or diphosphido complexes were obtained from the reaction of [(Dippnacnac)FeCl 2 Li(dme) 2 ] with the R 2 PLi (R = i Pr, t Bu, Cy, Ph) phosphides by tuning the stoichiometric ratio, polarity of the solvent, and the bulkiness of the substituents at the P‐atom. The structures of the synthesized compounds were determined by single‐crystal X‐ray diffraction, which revealed that the iron sites of the anionic complexes are four‐coordinate, whereas those of the neutral complexes are three‐coordinate with almost planar geometry. These phosphido iron complexes were also characterized by 1 H NMR and zero‐field Mössbauer spectroscopy. The thermal stability and reactivity of selected complexes were studied. The catalytic properties of the phosphido complexes were confirmed by investigating the conversion of diphenylphosphine to symmetrical 1,1,2,2‐teraphenyldiphosphane." @default.
- W2892028199 created "2018-09-27" @default.
- W2892028199 creator A5027568439 @default.
- W2892028199 creator A5030572389 @default.
- W2892028199 creator A5047008470 @default.
- W2892028199 creator A5054354490 @default.
- W2892028199 creator A5054574462 @default.
- W2892028199 creator A5084980550 @default.
- W2892028199 date "2018-10-08" @default.
- W2892028199 modified "2023-09-26" @default.
- W2892028199 title "Syntheses, Structures and Reactivity of Terminal Phosphido Complexes of Iron(II) Supported by a β‐Diketiminato Ligand" @default.
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