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• W2892035220 abstract "Abstract The gas phase IR spectra of α2,3 and α2,6 linkage isomers of sialic acid-containing human milk oligosaccharides and N-glycans epitopes are measured in the 3 µm spectral range using IRMPD spectroscopy in protonated and Na+ charge states. Each linkage isomer has a unique IRMPD fingerprint, providing a convenient diagnostic of the sialic acid position. Finally, a generic trend is observed: 3-linked sialic acid results in a significant broadening of the spectroscopic signature regardless of the glycan core and the charge state which suggests a drastic influence of the sialic acid position on the glycan conformation." @default.
• W2892035220 created "2018-09-27" @default.
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• W2892035220 date "2018-11-01" @default.
• W2892035220 modified "2023-09-30" @default.
• W2892035220 title "Identification of sialic acid linkage isomers in glycans using coupled InfraRed Multiple Photon Dissociation (IRMPD) spectroscopy and mass spectrometry" @default.
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• W2892035220 doi "https://doi.org/10.1016/j.ijms.2018.09.005" @default.
• W2892035220 hasPublicationYear "2018" @default.
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