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- W2892052421 abstract "A simple, expeditious and high‐efficiency synthetic method for the AlCl 3 ‐mediated one‐pot preparation of 2‐mercapto benzoheterocycles (2‐mercapto benzothiazoles, benzoxazoles and benzimidazoles) is described. By the treatment of a series of S, O and N heteroatoms containing bifunctional molecules with sodium dimethyldithiocarbamate in AlCl 3 , the desired benzoheterocycles are obtained smoothly. The protocol can also be applied on the synthesis of a series of thiazolidine‐2‐thiones, imidazolidine‐2‐thiones. This novel synthetic approach has advantages such as ligand‐free, high efficiency, short reaction time, readily available starting materials and simple experimental procedures." @default.
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- W2892052421 date "2018-10-10" @default.
- W2892052421 modified "2023-10-14" @default.
- W2892052421 title "AlCl<sub>3</sub> -Promoted Synthesis of 2-Mercapto Benzoheterocycles by Using Sodium Dimethyldithiocarbamate as Thiocarbonyl Surrogate" @default.
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- W2892052421 doi "https://doi.org/10.1002/ejoc.201800993" @default.
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