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- W2892064616 abstract "AbstractWe measured Raman spectra in crystals of molecular donor–acceptor fullerene complexes { Me ( n Pr_2 dtc )_2} · (C_60)_2 ( Me = Ni, Cu, Pt). In the spectra of the {Pt( n Pr_2 dtc )_2} · (C_60)_2 complex under prolonged irradiation with a laser with λ = 532 nm, characteristic changes in the photopolymerization of fullerene are observed, associated with the splitting of degenerate phonon Hg modes and softening of Ag modes of the C_60 molecule. The kinetics of photopolymerization under conditions of weak irradiation at room temperature is studied. It was found that thermal destruction of the photopolymer with increasing temperature leads to a decrease in its concentration in the final photopolymerization product. The kinetics of thermal destruction is described by the Arrhenius equation, with the activation energy E _A of (0.68 ± 0.03) eV; the dimers are destructed to a concentration of 1% within 15 min at ~114°C." @default.
- W2892064616 created "2018-09-27" @default.
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- W2892064616 date "2018-01-01" @default.
- W2892064616 modified "2023-10-05" @default.
- W2892064616 title "Фотополимеризация в слоях фуллерена молекулярного донорно-акцепторного комплекса Pt(nPr-=SUB=-2-=/SUB=-dtc)-=SUB=-2-=/SUB=-·(C-=SUB=-60-=/SUB=-)-=SUB=-2-=/SUB=-" @default.
- W2892064616 doi "https://doi.org/10.21883/ftt.2018.10.46539.119" @default.
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