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- W2892094110 abstract "Abstract Heating Ru3(CO)8(µ-dppm)(µ-dpam) (1) for 5 h in refluxing toluene resulted in the formation of Ru3(µ-H)(CO)7(µ3-PhPCH2PPh2(C6H4)As)(µ3-CHAsPh2) (2), Ru3(µ-H)(CO)7(µ3-PhPCHPPh(C6H4))(µ-dpam) (3), Ru3(CO)7(µ3-PPh)(µ3-CHPPh2)(µ-dpam) (4), Ru3(µ-CO)(CO)6(µ3-Ph2PCH2PPh)(µ3-Ph2AsCH2As(C6H4)Ph) (5) and Ru3(µ3-O)(µ3-CO)(CO)5(µ-dppm)(µ-dpam) (6). The reaction involves C–H, P–C and As–C bonds activation, elimination of benzene and unusual metalation of the P(C6H4)As. All the new clusters have been characterized by a combination of spectroscopic data and single crystal X-ray diffraction analysis." @default.
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- W2892094110 date "2018-11-01" @default.
- W2892094110 modified "2023-09-24" @default.
- W2892094110 title "Thermolysis of Ru3(CO)8(µ-dppm)(µ-dpam): Transformation of bis(diphenylphosphino)methane and bis(diphenylarsino)methane" @default.
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- W2892094110 doi "https://doi.org/10.1016/j.poly.2018.08.064" @default.
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