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- W2892107403 abstract "A new family of unsymmetrical, N,C-chelate organoboron compounds B(ppz)(Mes)Ar have been synthesized and found to undergo a rare, regioselective two-stage photoisomerization, involving the Ar group only. The initial transformation is a Zimmerman rearrangement to afford yellow azaboratabisnorcaradiene isomers that are subsequently converted to unprecedented 14aH-diazaborepins via a photochemical “walk” rearrangement. Spectroscopic and computational studies provide insight into the formation and properties of these unique systems." @default.
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- W2892107403 date "2018-09-20" @default.
- W2892107403 modified "2023-10-12" @default.
- W2892107403 title "Accessing Two-Stage Regioselective Photoisomerization in Unsymmetrical N,C-Chelate Organoboron Compounds: Reactivity of B(ppz)(Mes)Ar" @default.
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- W2892107403 doi "https://doi.org/10.1021/acs.organomet.8b00598" @default.
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