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- W2892190031 abstract "Molten salt [MNO3/NO2 (M = Li, Na, and K)]-promoted MgO composite-type CO2 adsorbents with high capacity and cycling stability are fabricated by controlled hydrolysis along with an incipient impregnation approach. The remarkable results of molten salts on the CO2 capture performance of MgO adsorbents and the CO2 capture capacities with different loadings and calcination and adsorption temperatures were comprehensively investigated. Notably, optimized NaNO3-promoted MgO exhibited the highest CO2 capture capacity of 17.0 mmol g–1 at 350 °C and maintained excellent regenerability through multiple cycles. The initial CO2 uptakes of MNO3/NO2 (M = Li, Na, and K)/MgO composites follow the order of NaNO3 (17.0 mmol g–1) > LiNO3 (14.1 mmol g–1) > NaNO2 (12.5 mmol g–1) > KNO2 (9.3 mmol g–1) > KNO3 (5.0 mmol g–1). Furthermore, NaNO3 and KNO3 with good chemical stability are the effective constituents for the NaNO3 system and KNO3/KNO2-promoted system, respectively, and preserved their original form after the interaction with CO2. The NaNO2 system consists of NaNO3 and Na2CO3 to form double carbonates Na2Mg(CO3)2 after CO2 adsorption. The morphology and structure of the MgO skeleton and the introduction of promoters are essential factors for intermediate-temperature CO2 capture." @default.
- W2892190031 created "2018-09-27" @default.
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- W2892190031 date "2018-09-07" @default.
- W2892190031 modified "2023-10-14" @default.
- W2892190031 title "Study on MNO<sub>3</sub>/NO<sub>2</sub> (M = Li, Na, and K)/MgO Composites for Intermediate-Temperature CO<sub>2</sub> Capture" @default.
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- W2892190031 doi "https://doi.org/10.1021/acs.energyfuels.8b02749" @default.
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