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• W2892193611 abstract "A general and transition-metal-free method for the construction of the carbazol-4-amine motif via a vinylogous Michael addition/cyclization/isomerization/elimination reaction of 3-nitroindoles with alkylidene malononitriles has been developed. This novel methodology allows the facile synthesis of a series of di- and trisubstituted carbazol-4-amine derivatives in moderate to good yields. A gram-scale experiment was successfully performed, highlighting the practicability of this method. Moreover, this strategy is also applicable to 3-nitrobenzothiophene, affording the corresponding dibenzo[b,d]thiophen-1-amine derivatives in moderate yields." @default.
• W2892193611 created "2018-09-27" @default.
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• W2892193611 date "2018-09-19" @default.
• W2892193611 modified "2023-10-14" @default.
• W2892193611 title "[4 + 2] Annulation of 3-Nitroindoles with Alkylidene Malononitriles: Entry to Substituted Carbazol-4-amine Derivatives" @default.
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• W2892193611 doi "https://doi.org/10.1021/acs.joc.8b01876" @default.
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