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- W2892236987 abstract "Abstract Photochemical reactions typically proceed via multiple reaction pathways, yielding a variety of isomers and products. Enhancing the selectivity is challenging. Now, the potential of supramolecular control for oxidative photocyclization of a tetraarylethylene, containing a stereogenic −C=C− bond, is demonstrated. In solution, this photochemical reaction produces three constitutional isomers (substituted phenanthrenes), with slow kinetics. When the reactant is assembled into a crystalline framework, only one product forms with accelerated kinetics. Key to this selectivity enhancement is the integration into a surface grown metal–organic framework (SURMOF); the dramatic gain in selectivity is ascribed to the hindrance of the rotational freedom of the −C=C− double bond. The structure of the MOF is key; the corresponding reaction in the solid does not result in such a high increase in selectivity. A striking change of luminescence properties after photocyclization is observed." @default.
- W2892236987 created "2018-09-27" @default.
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- W2892236987 date "2018-09-19" @default.
- W2892236987 modified "2023-10-18" @default.
- W2892236987 title "Enhancing Selectivity and Kinetics in Oxidative Photocyclization by Supramolecular Control" @default.
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- W2892236987 doi "https://doi.org/10.1002/anie.201806996" @default.
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