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- W2892271475 abstract "To investigate how central metal tunes the synergetic interactions between substituted metallo-phthalocyanine and single-walled carbon nanotubes in enhancing the gas sensing properties, a comparative study has been performed by varying the central metal ion in fluorinated metal phthalocyanines and single-walled carbon nanotube hybrid. Hybrids of metal(ii)-1,2,3,4,8,9,10,11,15,16,17,18-24,25-hexa-decafluoro-29H,31H-phthalocyanine/single-walled carbon nanotube (F16MPc/SWCNTs-COOH, where M = Co, Zn) have been synthesized through π-π stacking interactions using the solution route. Spectroscopic (FT-IR, UV-vis, XPS and Raman), electron microscopic (TEM and FE-SEM) and TGA investigations have confirmed the successful functionalization and interaction of SWCNTs-COOH with F16MPc. Parts per billion (ppb) level Cl2-selective chemiresistive gas sensors have been fabricated on glass substrates with precoated gold electrodes by using these hybrids. The responses of various F16MPc/SWCNTs-COOH sensors have demonstrated the central metal ion-dependence in the sensitivity of Cl2." @default.
- W2892271475 created "2018-09-27" @default.
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- W2892271475 date "2018-01-01" @default.
- W2892271475 modified "2023-10-06" @default.
- W2892271475 title "Tailoring of the chlorine sensing properties of substituted metal phthalocyanines non-covalently anchored on single-walled carbon nanotubes" @default.
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- W2892271475 doi "https://doi.org/10.1039/c8ra05529g" @default.
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