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- W2892298875 abstract "The Rh(III) catalyzed oxidation of 2-ketoglutaric acid by bromamine-T in acidmediumhas been studied. The reaction is first order each in bromamine - T and acid, less than unity order in both substrate and catalyst. The reaction constant is positive and increase with increase in temperature. The mechanism is influenced by participation of the neighboring group of 2- ketoglutaric, and intermolecular catalysis of Rh(III) is proposed. Insignificant effect of þ- toluenesulphonamide was observed. The processes are controlled by electron withdrawing and electron releasing substituents." @default.
- W2892298875 created "2018-09-27" @default.
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- W2892298875 date "2013-01-01" @default.
- W2892298875 modified "2023-09-24" @default.
- W2892298875 title "A kinetic and mechanistic study of Rh(III) catalysed oxidation of 2- ketoglutaric acid by bromamineÃÂT in acidic medium" @default.
- W2892298875 hasPublicationYear "2013" @default.
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