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- W2892313400 abstract "Surface modified hydroxyapatite/poly(ε-caprolactone) composites with comb-shaped poly (ε-caprolactone) (PCL) brushes grafted hydroxyapatite (n-HAP) were synthesized by a combination of atom transfer radical polymerization (ATRP) and ring-opening polymerization (ROP).,. Compared to the corresponding unmodified n-HAP/PCL composites, at modified n-HAP contents of 15 wt.% and 20% with a grafting ratio of 26.32%, the composites showed a maximum tensile modulus and elongation at break, flexural modulus and bending strength, respectively. This suggested that the comb-shaped PCL brushes at the interface are of advantage to the improvement of interfacial adhesion between the n-HAP and PCL polymer matrix by chain interdiffusion and entanglement with the PCL matrix. Furthermore, the observation should be attributed to the modified n-HAP particles, which were uniformly distributed in the polymer matrix and acted as heterogeneous nucleating agents during the crystallization of the PCL matrix." @default.
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- W2892313400 date "2012-06-01" @default.
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- W2892313400 title "Preparation and Characterization of Nanocomposites based on Poly(ε-caprolactone) and the Surface Grafted Nanohydroxyapatite with the Comb-shaped Poly(ε-caprolactone) Brushes" @default.
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- W2892313400 doi "https://doi.org/10.1177/096739111202000506" @default.
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