Matches in SemOpenAlex for { <https://semopenalex.org/work/W2892354042> ?p ?o ?g. }
- W2892354042 endingPage "662" @default.
- W2892354042 startingPage "654" @default.
- W2892354042 abstract "Thermal cis-trans isomerization of azobenzene and azopyridine derivatives was studied. The impact of the structural features of azo derivatives on its isomerization kinetics being important for molecular switching materials was investigated experimentally and theoretically based on the density-functional theory (DFT). Eleven azo-dyes in which the phenyl rings were substituted in the para-position to NN– linkage were prepared. Additionally, their thermal properties were evaluated by thermogravimetric analysis and differential scanning calorimetry. DFT calculations were also used for optimization ground and transition state geometries, the density of states, electronic structures of studied azo-dyes. The kinetics of the dark-return cis to trans-form of azo-compounds was investigated after UV-irradiation. It was found that attaching hydroxyalkoxy-substituents to the azo-dyes structure retarding the photoisomerization process in comparison to the hydroxyl group. Moreover, dark-return cis to trans-isomer was ca. twice times faster for azopyridine derivatives than for their azobenzene analogues. The calculated rate constants were in qualitative agreement with the experimental values." @default.
- W2892354042 created "2018-09-27" @default.
- W2892354042 creator A5008665605 @default.
- W2892354042 creator A5012921930 @default.
- W2892354042 creator A5022661483 @default.
- W2892354042 creator A5044297696 @default.
- W2892354042 creator A5057350763 @default.
- W2892354042 creator A5072057878 @default.
- W2892354042 creator A5073428158 @default.
- W2892354042 creator A5091158032 @default.
- W2892354042 date "2019-01-01" @default.
- W2892354042 modified "2023-10-15" @default.
- W2892354042 title "Fast dark cis-trans isomerization of azopyridine derivatives in comparison to their azobenzene analogues: Experimental and computational study" @default.
- W2892354042 cites W1869751432 @default.
- W2892354042 cites W1964599718 @default.
- W2892354042 cites W1966348302 @default.
- W2892354042 cites W1967719392 @default.
- W2892354042 cites W1988245896 @default.
- W2892354042 cites W1988978773 @default.
- W2892354042 cites W1996381594 @default.
- W2892354042 cites W2001562229 @default.
- W2892354042 cites W2006247709 @default.
- W2892354042 cites W2008847420 @default.
- W2892354042 cites W2016893951 @default.
- W2892354042 cites W2021502908 @default.
- W2892354042 cites W2022094095 @default.
- W2892354042 cites W2025396755 @default.
- W2892354042 cites W2040804962 @default.
- W2892354042 cites W2045132638 @default.
- W2892354042 cites W2046450560 @default.
- W2892354042 cites W2048082410 @default.
- W2892354042 cites W2049082818 @default.
- W2892354042 cites W2054306162 @default.
- W2892354042 cites W2058398316 @default.
- W2892354042 cites W2066072222 @default.
- W2892354042 cites W2068100138 @default.
- W2892354042 cites W2068837650 @default.
- W2892354042 cites W2068960354 @default.
- W2892354042 cites W2078823847 @default.
- W2892354042 cites W2080748422 @default.
- W2892354042 cites W2081030354 @default.
- W2892354042 cites W2086559314 @default.
- W2892354042 cites W2090176525 @default.
- W2892354042 cites W2093474509 @default.
- W2892354042 cites W2093713534 @default.
- W2892354042 cites W2101013774 @default.
- W2892354042 cites W2103639981 @default.
- W2892354042 cites W2106824077 @default.
- W2892354042 cites W2109492863 @default.
- W2892354042 cites W2124217672 @default.
- W2892354042 cites W2128759465 @default.
- W2892354042 cites W2143981217 @default.
- W2892354042 cites W2148212087 @default.
- W2892354042 cites W2151315653 @default.
- W2892354042 cites W2158047084 @default.
- W2892354042 cites W2159027933 @default.
- W2892354042 cites W2292896152 @default.
- W2892354042 cites W2338881018 @default.
- W2892354042 cites W2564371539 @default.
- W2892354042 cites W2588203092 @default.
- W2892354042 cites W2767922129 @default.
- W2892354042 cites W2770867823 @default.
- W2892354042 cites W2782588549 @default.
- W2892354042 cites W298949824 @default.
- W2892354042 cites W786094036 @default.
- W2892354042 doi "https://doi.org/10.1016/j.dyepig.2018.09.006" @default.
- W2892354042 hasPublicationYear "2019" @default.
- W2892354042 type Work @default.
- W2892354042 sameAs 2892354042 @default.
- W2892354042 citedByCount "35" @default.
- W2892354042 countsByYear W28923540422018 @default.
- W2892354042 countsByYear W28923540422019 @default.
- W2892354042 countsByYear W28923540422020 @default.
- W2892354042 countsByYear W28923540422021 @default.
- W2892354042 countsByYear W28923540422022 @default.
- W2892354042 countsByYear W28923540422023 @default.
- W2892354042 crossrefType "journal-article" @default.
- W2892354042 hasAuthorship W2892354042A5008665605 @default.
- W2892354042 hasAuthorship W2892354042A5012921930 @default.
- W2892354042 hasAuthorship W2892354042A5022661483 @default.
- W2892354042 hasAuthorship W2892354042A5044297696 @default.
- W2892354042 hasAuthorship W2892354042A5057350763 @default.
- W2892354042 hasAuthorship W2892354042A5072057878 @default.
- W2892354042 hasAuthorship W2892354042A5073428158 @default.
- W2892354042 hasAuthorship W2892354042A5091158032 @default.
- W2892354042 hasConcept C111233374 @default.
- W2892354042 hasConcept C121332964 @default.
- W2892354042 hasConcept C122865956 @default.
- W2892354042 hasConcept C126661725 @default.
- W2892354042 hasConcept C147597530 @default.
- W2892354042 hasConcept C147789679 @default.
- W2892354042 hasConcept C148898269 @default.
- W2892354042 hasConcept C152365726 @default.
- W2892354042 hasConcept C161790260 @default.
- W2892354042 hasConcept C178790620 @default.
- W2892354042 hasConcept C185592680 @default.
- W2892354042 hasConcept C2777307218 @default.
- W2892354042 hasConcept C2778150588 @default.