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• W2892359767 endingPage "6187" @default.
• W2892359767 startingPage "6183" @default.
• W2892359767 abstract "An iridium-catalyzed asymmetric allylation of dioxindoles, 3-hydroxyoxindoles, regulated by prosthetic groups has been accomplished under mild conditions. The methodology is applicable to a diverse array of 3-hydroxyoxindole and cinnamyl acetate substrates. A range of 3-allyl-3-hydroxyoxindoles containing vicinal tetrasubstituted and trisubstituted stereocenters can be efficiently synthesized in one-step with excellent enantioselectivity (up to >99% enaniomeric excess (ee)) and good diastereoselectivity (up to 11:1 diastereomeric ratio (dr))." @default.
• W2892359767 created "2018-09-27" @default.
• W2892359767 creator A5004152563 @default.
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• W2892359767 creator A5082306289 @default.
• W2892359767 creator A5087171358 @default.
• W2892359767 date "2018-09-21" @default.
• W2892359767 modified "2023-10-16" @default.
• W2892359767 title "Iridium-Catalyzed Enantioselective and Diastereoselective Allylation of Dioxindoles: A One-Step Synthesis of 3-Allyl-3-hydroxyoxindoles" @default.
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• W2892359767 doi "https://doi.org/10.1021/acs.orglett.8b02655" @default.
• W2892359767 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30240223" @default.
• W2892359767 hasPublicationYear "2018" @default.
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