Matches in SemOpenAlex for { <https://semopenalex.org/work/W2892375128> ?p ?o ?g. }
- W2892375128 endingPage "13807" @default.
- W2892375128 startingPage "13798" @default.
- W2892375128 abstract "A series of cage penta-arylated carboranes have been synthesized by palladium-catalyzed intermolecular coupling of the C-carboxylic acid of the monocarba- closo-dodecaborate anion [CB11H12]- with iodoarenes by direct cage B-H bond functionalization. These transformations set a record in terms of one-pot directing group-mediated activation of inert bonds in a single molecule. The methodology is characterized by high yields, good functional group tolerance, and complete cage regioselectivity. The directing group COOH can be easily removed during or after the intermolecular coupling reaction. The mechanistic pathways were probed using density functional theory calculations. A Pd(II)-Pd(IV)-Pd(II) catalytic cycle is proposed, in which initial coupling is followed by preferred B-H activation of the adjacent boron vertex, and continuation of this selectivity results in a continuous walking process of the palladium center. The methodology opens a new avenue toward building blocks with 5-fold symmetry." @default.
- W2892375128 created "2018-09-27" @default.
- W2892375128 creator A5000237955 @default.
- W2892375128 creator A5000311825 @default.
- W2892375128 creator A5002135335 @default.
- W2892375128 creator A5009790777 @default.
- W2892375128 creator A5030014001 @default.
- W2892375128 creator A5046333520 @default.
- W2892375128 creator A5049010282 @default.
- W2892375128 creator A5076671358 @default.
- W2892375128 date "2018-09-19" @default.
- W2892375128 modified "2023-10-17" @default.
- W2892375128 title "Palladium-Catalyzed Selective Five-Fold Cascade Arylation of the 12-Vertex Monocarborane Anion by B–H Activation" @default.
- W2892375128 cites W1823137473 @default.
- W2892375128 cites W1899802669 @default.
- W2892375128 cites W1924841364 @default.
- W2892375128 cites W1949559959 @default.
- W2892375128 cites W1968469772 @default.
- W2892375128 cites W1971641911 @default.
- W2892375128 cites W1973850019 @default.
- W2892375128 cites W1977800825 @default.
- W2892375128 cites W1981557359 @default.
- W2892375128 cites W1989080669 @default.
- W2892375128 cites W1992124690 @default.
- W2892375128 cites W1994496780 @default.
- W2892375128 cites W1994541961 @default.
- W2892375128 cites W1996659046 @default.
- W2892375128 cites W1997206792 @default.
- W2892375128 cites W1999305602 @default.
- W2892375128 cites W2010429942 @default.
- W2892375128 cites W2012759453 @default.
- W2892375128 cites W2012988700 @default.
- W2892375128 cites W2016061999 @default.
- W2892375128 cites W2021348611 @default.
- W2892375128 cites W2037586833 @default.
- W2892375128 cites W2040402142 @default.
- W2892375128 cites W2043337711 @default.
- W2892375128 cites W2057208900 @default.
- W2892375128 cites W2057390396 @default.
- W2892375128 cites W2069094014 @default.
- W2892375128 cites W2070235143 @default.
- W2892375128 cites W2072171392 @default.
- W2892375128 cites W2076629810 @default.
- W2892375128 cites W2076712933 @default.
- W2892375128 cites W2081015480 @default.
- W2892375128 cites W2081235448 @default.
- W2892375128 cites W2083267950 @default.
- W2892375128 cites W2084649760 @default.
- W2892375128 cites W2087046754 @default.
- W2892375128 cites W2090264815 @default.
- W2892375128 cites W2095864731 @default.
- W2892375128 cites W2110267483 @default.
- W2892375128 cites W2116820493 @default.
- W2892375128 cites W2117142379 @default.
- W2892375128 cites W2125014016 @default.
- W2892375128 cites W2125454909 @default.
- W2892375128 cites W2132615915 @default.
- W2892375128 cites W2133864760 @default.
- W2892375128 cites W2138529046 @default.
- W2892375128 cites W2144484723 @default.
- W2892375128 cites W2153317102 @default.
- W2892375128 cites W2160692933 @default.
- W2892375128 cites W2160790360 @default.
- W2892375128 cites W2168815589 @default.
- W2892375128 cites W2172395258 @default.
- W2892375128 cites W2186578812 @default.
- W2892375128 cites W2204898354 @default.
- W2892375128 cites W2294396756 @default.
- W2892375128 cites W2312547392 @default.
- W2892375128 cites W2315340528 @default.
- W2892375128 cites W2315380494 @default.
- W2892375128 cites W2318070594 @default.
- W2892375128 cites W2319062423 @default.
- W2892375128 cites W2322183551 @default.
- W2892375128 cites W2322963058 @default.
- W2892375128 cites W2323904430 @default.
- W2892375128 cites W2323997881 @default.
- W2892375128 cites W2324523966 @default.
- W2892375128 cites W2324625176 @default.
- W2892375128 cites W2326778858 @default.
- W2892375128 cites W2329305355 @default.
- W2892375128 cites W2333841311 @default.
- W2892375128 cites W2338096502 @default.
- W2892375128 cites W2339051409 @default.
- W2892375128 cites W2343107732 @default.
- W2892375128 cites W2347133646 @default.
- W2892375128 cites W2357889777 @default.
- W2892375128 cites W2396026222 @default.
- W2892375128 cites W2406091788 @default.
- W2892375128 cites W2415589628 @default.
- W2892375128 cites W2418203839 @default.
- W2892375128 cites W2471215336 @default.
- W2892375128 cites W2515509965 @default.
- W2892375128 cites W2519044780 @default.
- W2892375128 cites W2519935206 @default.
- W2892375128 cites W2523220278 @default.
- W2892375128 cites W2527889745 @default.
- W2892375128 cites W2529896803 @default.