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- W2892432568 abstract "A series of titanium complexes containing the permethylpentalene ligand (C8Me62−; Pn∗) – Pn∗Ti(O-2,6-Me-C6H3)Cl (1), Pn∗Ti(O-2,4-tBu-C6H3)Cl (2), Pn∗Ti(OtBu)Cl (3), Pn∗Ti(O-2,6-Me-C6H3)2 (4), Pn∗Ti(OtBu)2 (5) – or the (hydro)permethylpentalene ligand (C8Me6H−; Pn∗(H)) – Pn∗(H)Ti(O-2,6-Me-C6H3)Cl2 (6) and Pn∗(H)Ti(O-2,6-Me2-C6H3)3 (7) – were prepared by the reaction of [Pn∗TiCl(μ-Cl)]2 with the corresponding potassium salt or alcohol. All complexes have been characterized by single crystal X-ray diffraction studies and NMR spectroscopy. The (hydro)permethylpentalene complexes contain a stereocenter and planar chirality which can be described as R,RP or S,SP configurations." @default.
- W2892432568 created "2018-10-05" @default.
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- W2892432568 date "2019-01-01" @default.
- W2892432568 modified "2023-10-16" @default.
- W2892432568 title "Synthesis and characterization of permethylpentalene titanium aryloxide and alkoxide complexes" @default.
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- W2892432568 doi "https://doi.org/10.1016/j.poly.2018.09.068" @default.
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