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- W2892479771 abstract "ABSTRACT We studied the scaling behavior of the mesh size ( ) of chemically crosslinked poly( N ‐isopropylacrylamide‐ co ‐acrylic acid) hydrogels with changing crosslinker concentration ( C cl ) from 0.006 to 0.143 mol L −1 . Three experimental methods were employed, namely dynamic swelling, rheometry, and probe diffusion by pulsed gradient spin‐echo NMR. The mesh sizes determined by probe diffusion are dependent on the probe size. The scaling model of ( n < 0) could describe variation of the mesh size, obtained by any of the aforementioned techniques, with the crosslinker concentration. Thus, for hydrogels in equilibrium with water, the obtained values of the scaling exponent ( n ) are −0.73 ± 0.05 for dynamic swelling, −1.0 ± 0.3 for probe diffusion, and −0.27 ± 0.02 for rheological measurements. We demonstrated that the scaling of the mesh sizes for probe diffusion and dynamic swelling results was in good agreement with theoretical prediction. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135 , 46695." @default.
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- W2892479771 date "2018-09-27" @default.
- W2892479771 modified "2023-10-10" @default.
- W2892479771 title "Determining the scaling of gel mesh size with changing crosslinker concentration using dynamic swelling, rheometry, and PGSE NMR spectroscopy" @default.
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- W2892479771 doi "https://doi.org/10.1002/app.46695" @default.
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