Matches in SemOpenAlex for { <https://semopenalex.org/work/W2892494100> ?p ?o ?g. }
- W2892494100 endingPage "61" @default.
- W2892494100 startingPage "52" @default.
- W2892494100 abstract "A new generation of silver-based polymeric ionic liquid (PIL) sorbent coatings has been developed and applied in solid-phase microextraction (SPME). The new materials are based on ionic liquid monomers formed by cations containing the silver(I) ion coordinated with two 1-vinylimidazole ligands. Up to seven different silver-based PIL sorbent coatings were developed by polymerizing the silver-IL monomer in the presence of either silver bis[(trifluoromethyl)sulfonyl]imide, and/or a dicationic ionic liquid crosslinker. The obtained sorbent coatings were found to possess adequate thermal stability despite the presence of the silver(I) ions. Thermal desorption of the analytes at 175 °C was effectively used without any significant decrease in extraction efficiency. The developed sorbent coatings were used in two different applications: the determination of alkenes/alkynes via headspace SPME and the determination of unsaturated fatty acids using direct-immersion SPME. In the former approach, the silver-based PILs were particularly selective for the determination of unsaturated compounds with terminal double bonds such as 1,5-hexadiene, 2-methyl-1,5-hexadiene, and 1,8-nonadiene. A study of the extraction mechanism of the analytes to the sorbent coating revealed a competitive partitioning of the analytes. In the second approach, the most selective silver-based PILs were applied for the determination of oleic acid, linoleic acid, and linolenic acid. After proper optimization of the method, the coatings were found to be more or as sensitive as the commercial polydimethylsiloxane fiber. Limits of detection between 2.6 and 8.2 μg L-1 in ultrapure water and from 12 to 14 μg L-1 in tap water were obtained for the best silver-based PIL, with relative standard deviations lower than 13% in all cases at a spiked level of 160 μg L-1. Finally, the fiber was effectively applied for the analysis of rinse water from a dairy farm, with adequate detection of the analytes at concentrations between 52 and 179 μg L-1." @default.
- W2892494100 created "2018-10-05" @default.
- W2892494100 creator A5043446422 @default.
- W2892494100 creator A5070778623 @default.
- W2892494100 date "2019-01-01" @default.
- W2892494100 modified "2023-10-17" @default.
- W2892494100 title "Silver-based polymeric ionic liquid sorbent coatings for solid-phase microextraction: Materials for the selective extraction of unsaturated compounds" @default.
- W2892494100 cites W1423700954 @default.
- W2892494100 cites W1964458063 @default.
- W2892494100 cites W2014639723 @default.
- W2892494100 cites W2034284699 @default.
- W2892494100 cites W2037006903 @default.
- W2892494100 cites W2055792897 @default.
- W2892494100 cites W2055956912 @default.
- W2892494100 cites W2057483243 @default.
- W2892494100 cites W2061729780 @default.
- W2892494100 cites W2063070426 @default.
- W2892494100 cites W2063153354 @default.
- W2892494100 cites W2081386483 @default.
- W2892494100 cites W2141904929 @default.
- W2892494100 cites W2291927264 @default.
- W2892494100 cites W2304662567 @default.
- W2892494100 cites W2510584973 @default.
- W2892494100 cites W2592597965 @default.
- W2892494100 cites W2627017949 @default.
- W2892494100 cites W2702582144 @default.
- W2892494100 cites W2766151475 @default.
- W2892494100 cites W2767489832 @default.
- W2892494100 cites W2771018033 @default.
- W2892494100 cites W2789947392 @default.
- W2892494100 cites W2800440862 @default.
- W2892494100 cites W2806262599 @default.
- W2892494100 cites W817004456 @default.
- W2892494100 cites W821127453 @default.
- W2892494100 cites W1974354948 @default.
- W2892494100 doi "https://doi.org/10.1016/j.aca.2018.09.051" @default.
- W2892494100 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30567664" @default.
- W2892494100 hasPublicationYear "2019" @default.
- W2892494100 type Work @default.
- W2892494100 sameAs 2892494100 @default.
- W2892494100 citedByCount "28" @default.
- W2892494100 countsByYear W28924941002018 @default.
- W2892494100 countsByYear W28924941002019 @default.
- W2892494100 countsByYear W28924941002020 @default.
- W2892494100 countsByYear W28924941002021 @default.
- W2892494100 countsByYear W28924941002022 @default.
- W2892494100 countsByYear W28924941002023 @default.
- W2892494100 crossrefType "journal-article" @default.
- W2892494100 hasAuthorship W2892494100A5043446422 @default.
- W2892494100 hasAuthorship W2892494100A5070778623 @default.
- W2892494100 hasConcept C150394285 @default.
- W2892494100 hasConcept C154881586 @default.
- W2892494100 hasConcept C161790260 @default.
- W2892494100 hasConcept C162356407 @default.
- W2892494100 hasConcept C162711632 @default.
- W2892494100 hasConcept C166940927 @default.
- W2892494100 hasConcept C178790620 @default.
- W2892494100 hasConcept C185592680 @default.
- W2892494100 hasConcept C205345274 @default.
- W2892494100 hasConcept C2777899863 @default.
- W2892494100 hasConcept C2778533135 @default.
- W2892494100 hasConcept C2781059571 @default.
- W2892494100 hasConcept C43617362 @default.
- W2892494100 hasConcept C4725764 @default.
- W2892494100 hasConcept C521977710 @default.
- W2892494100 hasConcept C81426234 @default.
- W2892494100 hasConceptScore W2892494100C150394285 @default.
- W2892494100 hasConceptScore W2892494100C154881586 @default.
- W2892494100 hasConceptScore W2892494100C161790260 @default.
- W2892494100 hasConceptScore W2892494100C162356407 @default.
- W2892494100 hasConceptScore W2892494100C162711632 @default.
- W2892494100 hasConceptScore W2892494100C166940927 @default.
- W2892494100 hasConceptScore W2892494100C178790620 @default.
- W2892494100 hasConceptScore W2892494100C185592680 @default.
- W2892494100 hasConceptScore W2892494100C205345274 @default.
- W2892494100 hasConceptScore W2892494100C2777899863 @default.
- W2892494100 hasConceptScore W2892494100C2778533135 @default.
- W2892494100 hasConceptScore W2892494100C2781059571 @default.
- W2892494100 hasConceptScore W2892494100C43617362 @default.
- W2892494100 hasConceptScore W2892494100C4725764 @default.
- W2892494100 hasConceptScore W2892494100C521977710 @default.
- W2892494100 hasConceptScore W2892494100C81426234 @default.
- W2892494100 hasLocation W28924941001 @default.
- W2892494100 hasLocation W28924941002 @default.
- W2892494100 hasOpenAccess W2892494100 @default.
- W2892494100 hasPrimaryLocation W28924941001 @default.
- W2892494100 hasRelatedWork W1970363878 @default.
- W2892494100 hasRelatedWork W1976392566 @default.
- W2892494100 hasRelatedWork W1986471711 @default.
- W2892494100 hasRelatedWork W2008585851 @default.
- W2892494100 hasRelatedWork W2037904089 @default.
- W2892494100 hasRelatedWork W2064938496 @default.
- W2892494100 hasRelatedWork W2109930380 @default.
- W2892494100 hasRelatedWork W2998016129 @default.
- W2892494100 hasRelatedWork W4200256891 @default.
- W2892494100 hasRelatedWork W4312139910 @default.
- W2892494100 hasVolume "1047" @default.
- W2892494100 isParatext "false" @default.