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• W2892651100 abstract "In this work, nanoporous carbon was synthesized from direct pyrolysis of ZIF-8, and the capacity fading of nanoporous carbon anode was explored. The structure, crystal phase, pore texture and elemental bonding were characterized by using scanning electron microscopy, X-ray diffraction, N2 adsorption-desorption and X-ray photoelectron spectroscopy, respectively. When employed as anode for lithium ions batteries, the nanoporous carbon derived from ZIF-8 owns outstanding discharge capacity of 3164 mAh/g during the first circle. However, the charge capacity fades to 1347 mAh/g and the reversible capacity is only 42.57%. We have found that the structure damage and irreversible alloying reaction during insertion-desertion of lithium ions are responsible for this phenomenon. Innovatively, introduced density functional theory provides crucial proofs about capacity mechanism for N-doped graphene based nanoporous carbon anode of lithium-ion batteries." @default.
• W2892651100 created "2018-10-05" @default.
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• W2892651100 date "2018-11-01" @default.
• W2892651100 modified "2023-10-15" @default.
• W2892651100 title "Capacity fading of nanoporous carbon electrode derived from ZIF-8 during insertion-desertion of lithium ions" @default.
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• W2892651100 doi "https://doi.org/10.1016/j.cplett.2018.09.051" @default.
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