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• W2892741775 abstract "Three-dimensional (3D) flower-like Co2(OH)3Cl-MnO2 nanostructures were fabricated inside eggshell through a facile and effective method. Inspired by semipermeable membranes, a shell membrane was selected as an interface for ion diffusion. In specific, an eggshell with shell membrane was employed as a multifunctional reactor to separate the components of the precursor solution. OH- ion diffusion was performed through porous eggshell membrane. The electrochemical measurements demonstrated that the hybrid composite achieves high capacitance 3.709 F/cm2 at 1 mA/cm2 (2061 F/g with the mass loading of 1.8 mg/cm2) and an excellent cycling stability (71% specific capacitance retained after 5000 cycle numbers), exhibiting a superior electrochemical performance compared to pure Co2(OH)3Cl or MnO2. Moreover, an asymmetric supercapacitor was assembled by Co2(OH)3Cl-MnO2-2 and activated carbon as positive and negative electrode, respectively (Co2(OH)3Cl-MnO2-2//AC ASC), which exhibits high capacitance (134.8 F/g at 0.2 A/g), excellent energy density (42.2 W h/kg at 150.3 W/kg), and remarkable cycling stability (80% capacitance retention after consecutive 5000 cycle numbers)." @default.
• W2892741775 created "2018-10-05" @default.
• W2892741775 creator A5010959343 @default.
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• W2892741775 date "2019-01-01" @default.
• W2892741775 modified "2023-09-27" @default.
• W2892741775 title "Shell membrane-aided synthesis of 3D porous flower-like Co2(OH)3Cl-MnO2 hybrid composites for high performance supercapacitors" @default.
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• W2892741775 doi "https://doi.org/10.1016/j.ceramint.2018.09.242" @default.
• W2892741775 hasPublicationYear "2019" @default.
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