FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2892800396> ?p ?o ?g. }

• W2892800396 endingPage "120049" @default.
• W2892800396 startingPage "120049" @default.
• W2892800396 abstract "Microkinetic analysis combined with the results obtained from density functional theory calculations has been performed to examine the catalytic activity and selectivity of Pt-based core-shell alloy catalysts for propane dehydrogenation. Calculated results indicate that substitution of 11 late transition metals for the core region of Pt nanoparticles would significantly modify the electronic structure of the surface Pt atoms through the strain effect and charge transfer. The core-shell catalysts are found to have less negative propylene adsorption energies and higher activation energies for the dehydrogenation reactions than Pt, thus giving rise to a lower catalytic activity and a higher selectivity toward propylene. Linear chemisorption energy and transition state energy scaling relations hold very well in the present work, and the adsorption energy of propylene is identified to be a good descriptor to represent the overall kinetics. The scaling relations also suggest that a higher catalyst selectivity toward propylene can only be achieved at the expense of a lower catalytic activity for propane dehydrogenation. If a compromise is made between catalytic activity and catalyst selectivity, [email protected] is proposed to be the best core-shell catalyst for propane dehydrogenation." @default.
• W2892800396 created "2018-10-05" @default.
• W2892800396 creator A5017774638 @default.
• W2892800396 creator A5033041178 @default.
• W2892800396 creator A5036123085 @default.
• W2892800396 creator A5043284449 @default.
• W2892800396 creator A5054831684 @default.
• W2892800396 creator A5067153584 @default.
• W2892800396 creator A5070597268 @default.
• W2892800396 creator A5085673398 @default.
• W2892800396 date "2019-12-01" @default.
• W2892800396 modified "2023-10-16" @default.
• W2892800396 title "Improved selectivity and coke resistance of core-shell alloy catalysts for propane dehydrogenation from first principles and microkinetic analysis" @default.
• W2892800396 cites W1128185712 @default.
• W2892800396 cites W1528588768 @default.
• W2892800396 cites W1529864833 @default.
• W2892800396 cites W1732273204 @default.
• W2892800396 cites W1970127494 @default.
• W2892800396 cites W1972725254 @default.
• W2892800396 cites W1973634181 @default.
• W2892800396 cites W1974742056 @default.
• W2892800396 cites W1976600523 @default.
• W2892800396 cites W1977187595 @default.
• W2892800396 cites W1978607450 @default.
• W2892800396 cites W1978885192 @default.
• W2892800396 cites W1979544533 @default.
• W2892800396 cites W1981368803 @default.
• W2892800396 cites W1985960755 @default.
• W2892800396 cites W1991114008 @default.
• W2892800396 cites W1991630775 @default.
• W2892800396 cites W1996923858 @default.
• W2892800396 cites W2002091475 @default.
• W2892800396 cites W2004751437 @default.
• W2892800396 cites W2007395042 @default.
• W2892800396 cites W2007740449 @default.
• W2892800396 cites W2011158115 @default.
• W2892800396 cites W2016355541 @default.
• W2892800396 cites W2016366655 @default.
• W2892800396 cites W2022085321 @default.
• W2892800396 cites W2030914019 @default.
• W2892800396 cites W2032364562 @default.
• W2892800396 cites W2033033223 @default.
• W2892800396 cites W2036113194 @default.
• W2892800396 cites W2040837725 @default.
• W2892800396 cites W2044483611 @default.
• W2892800396 cites W2047182805 @default.
• W2892800396 cites W2049126927 @default.
• W2892800396 cites W2052502921 @default.
• W2892800396 cites W2058891100 @default.
• W2892800396 cites W2064807075 @default.
• W2892800396 cites W2065251521 @default.
• W2892800396 cites W2067627076 @default.
• W2892800396 cites W2069843142 @default.
• W2892800396 cites W2069988560 @default.
• W2892800396 cites W2079105963 @default.
• W2892800396 cites W2079211716 @default.
• W2892800396 cites W2080596441 @default.
• W2892800396 cites W2083125409 @default.
• W2892800396 cites W2083222334 @default.
• W2892800396 cites W2088400298 @default.
• W2892800396 cites W2105081100 @default.
• W2892800396 cites W2117636074 @default.
• W2892800396 cites W2134943975 @default.
• W2892800396 cites W2159742564 @default.
• W2892800396 cites W2266857409 @default.
• W2892800396 cites W2279036584 @default.
• W2892800396 cites W2300293328 @default.
• W2892800396 cites W2306425811 @default.
• W2892800396 cites W2328928309 @default.
• W2892800396 cites W2332730447 @default.
• W2892800396 cites W2335124716 @default.
• W2892800396 cites W2398810131 @default.
• W2892800396 cites W2520033914 @default.
• W2892800396 cites W2556268107 @default.
• W2892800396 cites W2605096995 @default.
• W2892800396 cites W2755322751 @default.
• W2892800396 cites W2756021067 @default.
• W2892800396 cites W2762858198 @default.
• W2892800396 cites W2794826490 @default.
• W2892800396 cites W2799311380 @default.
• W2892800396 doi "https://doi.org/10.1016/j.cej.2018.09.210" @default.
• W2892800396 hasPublicationYear "2019" @default.
• W2892800396 type Work @default.
• W2892800396 sameAs 2892800396 @default.
• W2892800396 citedByCount "37" @default.
• W2892800396 countsByYear W28928003962020 @default.
• W2892800396 countsByYear W28928003962021 @default.
• W2892800396 countsByYear W28928003962022 @default.
• W2892800396 countsByYear W28928003962023 @default.
• W2892800396 crossrefType "journal-article" @default.
• W2892800396 hasAuthorship W2892800396A5017774638 @default.
• W2892800396 hasAuthorship W2892800396A5033041178 @default.
• W2892800396 hasAuthorship W2892800396A5036123085 @default.
• W2892800396 hasAuthorship W2892800396A5043284449 @default.
• W2892800396 hasAuthorship W2892800396A5054831684 @default.
• W2892800396 hasAuthorship W2892800396A5067153584 @default.
• W2892800396 hasAuthorship W2892800396A5070597268 @default.
• W2892800396 hasAuthorship W2892800396A5085673398 @default.

• next