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- W2892824712 abstract "A study of the species involved in the extraction of metalions from aqueous solutions into organic solvents with long-chaincarboxylic acids has been made.The theoretical analysis of the extraction data in terms of asingle equilibrium approach and a multiple equilibria method has beenmade. The two approaches have been shown to be equivalent in thecase of one extracted complex, and an extraction expression has beenproposed to describe the extractions. The analysis of the data hasbeen considered in terms of this expression by graphical andregression procedures.Under the equilibrium extraction conditions studied, theextracted species in the case of copper (II), cobalt (II) and nickel(II) systems appear to be predominantly dimeric in nature and areusually solvated with carboxylic acid molecules in the organic phase.Results obtained from the extraction of copper from anaqueous solution into free-falling drops of n-octoic acid dissolvedin carbon tetrachloride indicate that the rate of extraction doesnot vary appreciably over the pH range studied. The measurementof the interfacial tensions in the same system suggests that noabrupt change in the nature of the interfacial region occurs as thepH of extraction increases." @default.
- W2892824712 created "2018-10-05" @default.
- W2892824712 creator A5009905166 @default.
- W2892824712 date "1967-01-01" @default.
- W2892824712 modified "2023-09-27" @default.
- W2892824712 title "A study of the mechanism of the solvent extraction of metal ions by carboxylic acids" @default.
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- W2892824712 hasPublicationYear "1967" @default.
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